A Theoretical Interpretation Of Polarographic Studies Of The Cadmium Complexes of Thiourea and Methylthiourea In Dioxane-Water Mixtures
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Authors
Connolly, John
Advisor
James Ryan
Editor
Date of Issue
1956-04-01
Subject Keywords
Publisher
Citation
Series/Report No.
item.page.identifier
Title
A Theoretical Interpretation Of Polarographic Studies Of The Cadmium Complexes of Thiourea and Methylthiourea In Dioxane-Water Mixtures
Other Titles
Type
thesis
Description
Abstract
The purposes of this work ares a) to determine the stability constants for complexes of thiourea and methylthiourea with cadmium (II) ion by applying a definite correction factor to the best existing determination (1); and b) to explain the results on the basis of accepted theories (2).
The experimental information was obtained from the Ph.D. thesis of Ryan (1), who used thiourea and 1-methyl-2-thiourea as complexing agents. The solvent system used was 50% dioxane-50% water, (% by volume). Where ligand solubilities permitted, similar data were obtained from studies involving aqueous systems for comparative purposes.The purposes of this work ares a) to determine the stability constants for complexes of thiourea and methylthiourea with cadmium (II) ion by applying a definite correction factor to the best existing determination (1); and b) to explain the results on the basis of accepted theories (2).
The experimental information was obtained from the Ph.D. thesis of Ryan (1), who used thiourea and 1-methyl-2-thiourea as complexing agents. The solvent system used was 50% dioxane-50% water, (% by volume). Where ligand solubilities permitted, similar data were obtained from studies involving aqueous systems for comparative purposes.
Sponsors
Degree Awarded
Bachelor's
Semester
Spring
Department
Chemistry & Physics