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    A Theoretical Interpretation Of Polarographic Studies Of The Cadmium Complexes of Thiourea and Methylthiourea In Dioxane-Water Mixtures

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    Author
    Connolly, John
    Advisor
    James Ryan
    Date of Issue
    1956-04-01
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    URI
    https://scholars.carroll.edu/handle/20.500.12647/192
    Title
    A Theoretical Interpretation Of Polarographic Studies Of The Cadmium Complexes of Thiourea and Methylthiourea In Dioxane-Water Mixtures
    Type
    thesis
    Abstract
    The purposes of this work ares a) to determine the stability constants for complexes of thiourea and methylthiourea with cadmium (II) ion by applying a definite correction factor to the best existing determination (1); and b) to explain the results on the basis of accepted theories (2). The experimental information was obtained from the Ph.D. thesis of Ryan (1), who used thiourea and 1-methyl-2-thiourea as complexing agents. The solvent system used was 50% dioxane-50% water, (% by volume). Where ligand solubilities permitted, similar data were obtained from studies involving aqueous systems for comparative purposes.The purposes of this work ares a) to determine the stability constants for complexes of thiourea and methylthiourea with cadmium (II) ion by applying a definite correction factor to the best existing determination (1); and b) to explain the results on the basis of accepted theories (2). The experimental information was obtained from the Ph.D. thesis of Ryan (1), who used thiourea and 1-methyl-2-thiourea as complexing agents. The solvent system used was 50% dioxane-50% water, (% by volume). Where ligand solubilities permitted, similar data were obtained from studies involving aqueous systems for comparative purposes.
    Degree Awarded
    Bachelor's
    Semester
    Spring
    Department
    Chemistry & Physics
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    • Chemistry and Physics Undergraduate Theses

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